Physical and Chemical Properties of a New Poly(Ionic Liquid)
Collections
Résumé
The present work aimed to understand the physical and chemical properties of a
vinylbenzylimidazolium-based poly (ionic liquid), while also examining how three distinct
counter-anions influence these properties. Therefore, the monomer VBmim-Cl and poly
(VBmim-Cl) were synthesized and conducted with anionic metathesis using NTF2-, and PF6-.
NMR spectroscopy, FTIR-ATR and Raman spectroscopy and TGA/DSC analysis were
employed to investigate the structure, vibrational and thermal properties. Additionally, TGA
and DSC analysis reveal that the anion nature and the polymerization procedure affected the
thermal stability and the glass transition temperature values of the samples.